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- Title
Cover Feature: Structural Insights into Hysteretic Spin‐Crossover in a Set of Iron(II)‐2,6‐bis(1H‐Pyrazol‐1‐yl)Pyridine) Complexes (Chem. Eur. J. 6/2022).
- Authors
Suryadevara, Nithin; Mizuno, Asato; Spieker, Lea; Salamon, Soma; Sleziona, Stephan; Maas, André; Pollmann, Erik; Heinrich, Benoît; Schleberger, Marika; Wende, Heiko; Kuppusamy, Senthil Kumar; Ruben, Mario
- Abstract
The large structural reorganizations from the Jahn-Teller-distorted high-spin state to the less distorted low-spin state and ethyl group conformational switching are proposed as the main contributing factors rendering the switching hysteretic. Cover Feature: Structural Insights into Hysteretic Spin-Crossover in a Set of Iron(II)-2,6-bis(1H-Pyrazol-1-yl)Pyridine) Complexes (Chem. Eur. J. 6/2022) Keywords: Spin-crossover; X-ray diffraction; Jahn-Teller distortion; thermal hysteresis; molecular devices EN Spin-crossover X-ray diffraction Jahn-Teller distortion thermal hysteresis molecular devices 1 1 1 02/01/22 20220127 NES 220127 B Bistable spin-state switching near room temperature b : Two mononuclear iron(II) complexes showing technologically relevant abrupt and wide hysteretic, bistable spin-state switching characteristics in the vicinity of room temperature are reported.
- Subjects
PYRIDINE; IRON; SPIN crossover; ETHYL group; X-ray diffraction
- Publication
Chemistry - A European Journal, 2022, Vol 28, Issue 6, p1
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202103853