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- Title
Trendbericht Anorganik 2024: Nebengruppen, Bioanorganik und Koordinationschemie.
- Authors
Kreidt, Elisabeth; Werncke, Gunnar
- Abstract
The trend report Inorganic 2024 covers various topics in the field of inorganic chemistry. Highlights include the lightest metal-metal bond in bisberyllocene and unusually reactive species such as a crystalline triplet bismuthinide. Furthermore, investigations on C-H activation using X-ray absorption spectroscopy and the isolation of 17-valence electron complexes of group 7 are described. Other topics include square-planar complexes in platinum(0) and cobalt(II), the formation of cobalt-tin and cobalt-lead triple bonds, as well as the synthesis of complex representatives with heavy tetraphosphilide ions. Nitrido, phosphido, and imido complexes, as well as catalysis and ethylene polymerization, are also addressed. This text summary deals with various topics in chemical research, examining mechanisms and reactions related to metal complexes and catalysts. Various metals such as molybdenum, nickel, copper, and iron are considered, and their role in the activation and transformation of molecules such as alkynes, nitrates, and nitrogen compounds is investigated. Additionally, photophysical and photochemical processes involving readily available metals are examined. The summary provides an overview of the different topics and research findings covered in the text. The article presents various complex compounds with rare earth and f-elements. The group led by Heinze, Kitzmann, and colleagues introduces the new Mo0 complex Mo(CO)3(tpe), which is more photostable than [Ru(bpy)3]2+. The group led by Strassert reports on PdII and PtII complexes with a new ligand that acts as a double cyclometallizing agent. The group led by Murugesu reports on a highly angled YbIII complex with single-molecule magnet properties. Other complex compounds with rare earth and f-elements are presented, including lanthanoid-bismuth cluster compounds and compounds with pnictogens or chalcogens. Progress in handling hard-to-access actinides and their utilization by bacterial strains is also discussed.
- Subjects
COMPLEX compounds; PLATINUM; NITROGEN compounds; COPPER; INORGANIC chemistry; SINGLE molecule magnets
- Publication
Nachrichten aus der Chemie, 2024, Vol 72, Issue 2, p58
- ISSN
1439-9598
- Publication type
Article
- DOI
10.1002/nadc.20244140475