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- Title
Metall‐Ligand‐Kooperativität: Gemeinsam stärker.
- Authors
Hadlington, Terrance
- Abstract
In the article "Metal-Ligand Cooperativity: Stronger Together," Terrance Hadlington turns the concept of metal-ligand cooperativity on its head and seeks systems that can achieve hydroamination of alkenes with ammonia. The research focuses on ligand design, as it has the greatest influence on homogeneous catalysis. A specific approach is the use of single-center ambiphiles (SCA), which contain both Lewis acidic and Lewis basic groups. By using heavier elements from groups 13 and 14, Lewis acidity can be enhanced, leading to higher reactivity. SCA transition metal complexes are suitable catalysts for various chemical transformations such as the addition of ammonia to alkenes and the hydrogenation of alkenes. Terrance Hadlington is a Liebig fellow and group leader at the Technical University of Munich.
- Subjects
TECHNISCHE Universitat Munchen; CHEMICAL amplification; GROUP 13 elements; TRANSITION metal complexes; HOMOGENEOUS catalysis; LEWIS acidity; TRANSITION metal catalysts; ATMOSPHERIC ammonia
- Publication
Nachrichten aus der Chemie, 2023, Vol 71, Issue 7, p64
- ISSN
1439-9598
- Publication type
Article
- DOI
10.1002/nadc.20234137313