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- Title
Highly Efficient One-Step Synthesis of N-Trimethylsiloxy Alkyl Imidothioates.
- Authors
Kuciński, Krzysztof; Hreczycho, Grzegorz
- Abstract
A hitherto unknown synthetic pathway for the synthesis of N-trimethylsiloxy alkyl imidothioates has been presented. The catalyst-free route uses a range of aromatic, aliphatic, and heterocyclic thiols in the presence of nitroalkanes and hexamethyldisilazane (HMDS). This unusual method expands upon the knowledge of nitro compounds and demonstrates their importance not only as solvents but also as valuable organic reagents. This reaction proceeds under mild conditions and is characterized by excellent yields and a facile workup.
- Subjects
CATALYSTS; NITROALKANES; HETEROCYCLIC compounds; NITRO compounds; OXIMES
- Publication
European Journal of Organic Chemistry, 2016, Vol 2016, Issue 26, p4577
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201600768