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- Title
Synthesis and crystal structure of trans-[Ru(NO)(NH)SO]ClO and [Ru(NO)(NH)SO][Ru(NO)(NH)Cl(SO)]HSO•HO.
- Authors
Makhinya, A.; Il'in, M.; Baidina, I.; Korol'kov, I.
- Abstract
After the addition of the saturated NaClO solution to a solution of trans-[Ru(NO)(NH)SO]HSO•HO, trans-[Ru(NO)(NH)SO]ClO perchlorate salt ( I) is obtained with the yield of ~80%. The heating of trans-[Ru(NO)(NH)(HO)](HSO)SO at a temperature of ~220 °C results in a complete removal of coordination water and a partial removal of ammonia molecules. Successive treatment of the thermolysis product with sulfuric and hydrochloric acids yields [Ru(NO)(NH)SO][Ru(NO)(NH)Cl(SO)]HSO•HO crystals ( II). The single crystal X-ray diffraction method is used to determine the structure of the compounds obtained. For I: space group P2/ c, a = 6.6949(9) Å, b = 13.7049(19) Å, c = 12.8641(17) Å, β = 101.028(4)°; for II: space group Р2/ c, a = 14.1304(4) Å, b = 12.4908(3) Å,, c = 11.6264(3) Å, β = 94.1980(10)°.
- Subjects
RUTHENIUM compounds; CRYSTAL structure; PHASE transitions; SOLUTION (Chemistry); TEMPERATURE effect; COORDINATE covalent bond
- Publication
Journal of Structural Chemistry, 2016, Vol 57, Issue 6, p1182
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S0022476616060184