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- Title
Distannadithiophenes and Their Application towards Hydroboration of Carbonyl Compounds.
- Authors
Sa, Shreenibasa; Ponniah, Joseph S.; Biswal, Priyabrata; Sathesh, Venkatesan; Murali, Anna Chandrasekar; Venkatasubbaiah, Krishnan
- Abstract
Synthesis of distannadithiophenes (C6H6S)2Sn2Ar4) with different aryl substituents is presented. These air‐stable distannadithiophenes were tested as catalysts for the hydroboration of carbonyl compounds. Among the different distannadithiophenes tested, tetra‐tolyl distannadithiophene showed better catalytic activity over other compounds. A wide variety of aldehydes and ketones were reduced to their corresponding boronate esters using tetra‐tolyl distannadithiophene as a catalyst at room temperature.
- Subjects
CARBONYL compounds; HYDROBORATION; BORONIC esters; CATALYTIC activity; CATALYST testing
- Publication
European Journal of Inorganic Chemistry, 2022, Vol 2022, Issue 25, p1
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.202200283