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- Title
Synthesis and Characterisation of Heterobimetallic Lanthanoid O-Based Cluster/Cages.
- Authors
Andrews, Philip C.; Bousrez, Guillaume; Junk, Peter C.; Thielemann, Dominique T.; Werrett, Melissa V.
- Abstract
The synthesis of new mono- and bimetallic lanthanoid cluster compounds is reported. The metal-to metal ratios of tetra- and pentanuclear clusters were determined by energy-dispersive X-ray spectroscopy (EDS). The EDS results show that, for an equal proportion of lanthanide salts introduced, different metal-to-metal ratios are achieved in the clusters. This ratio appears to be dependent on the size and electron density of the metal atoms. Studies realized the best conditions to achieve a 1:1 ratio.
- Subjects
HETEROBIMETALLIC complexes; RARE earth metal compound synthesis; ENERGY dispersive X-ray spectroscopy; ELECTRON density; SALTS; OXYGEN compounds
- Publication
European Journal of Inorganic Chemistry, 2017, Vol 2017, Issue 3, p679
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201601264