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- Title
Remarkable two-step, four-electron oxidative addition reactions at phosphorus [P(I)–P(V)] in terminal electrophilic phosphinidene complexes.
- Authors
Graham, Todd W.; Udachin, Konstantin A.; Zgierski, Marek Z.; Carty, Arthur J.
- Abstract
The reactivity of the terminal phosphinidene complex [Re(CO)5{η1-P(NiPr2)}]AlCl4 towards the oxidants S8 and Me3SnN3 has been investigated. These result in unprecedented four-electron oxidative addition reactions, affording complexes containing the P(V) ligands η1-P(=S)(Cl)(NiPr2) and η1-P(=NR)(Cl)(NiPr2), respectively. DFT calculations support the proposed mechanism.
- Subjects
PHOSPHINE; OXIDES; ELECTRONS; CHEMICAL reactions; OXIDIZING agents
- Publication
Canadian Journal of Chemistry, 2007, Vol 85, Issue 10, p885
- ISSN
0008-4042
- Publication type
Article
- DOI
10.1139/V07-119