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- Title
Global Warming Potentials for the C<sub>1</sub>-C<sub>3</sub> Hydrochlorofluorocarbons (HCFCs) Included in the Kigali Amendment to the Montreal Protocol.
- Authors
Papanastasiou, Dimitrios K.; Beltrone, Allison; Marshall, Paul; Burkholder, James B.
- Abstract
Hydrochlorofluorocarbons (HCFCs) are ozone depleting substances and potent greenhouse gases that are controlled under the Montreal Protocol. However, the majority of the 274 HCFCs included in Annex C of the protocol do not have reported global warming potentials (GWPs) that are used to guide the phase-out of HCFCs and the future phase-down of hydrofluorocarbons (HFCs). In this study, GWPs for all C1-C3 HCFCs included in Annex C are reported based on estimated atmospheric lifetimes and theoretical methods used to calculate infrared absorption spectra. Atmospheric lifetimes were estimated from a structure activity relationship (SAR) for OH radical reactivity and estimated O(1D) reactivity and UV photolysis loss processes. The HCFCs display a wide range of lifetimes and GWPs dependent on their molecular structure and H-atom content of the individual HCFC. The results from this study provide reliable policy relevant GWP metrics for the HCFCs included in the Montreal Protocol in the absence of experimentally derived metrics.
- Subjects
HYDROCHLOROFLUOROCARBONS; GLOBAL warming; VIENNA Convention for the Protection of the Ozone Layer (1985). Protocols, etc., 1987 Sept. 15; ABSORPTION spectra; REACTIVITY (Chemistry)
- Publication
Atmospheric Chemistry & Physics Discussions, 2018, p1
- ISSN
1680-7367
- Publication type
Article
- DOI
10.5194/acp-2018-27