We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Crystallization-Induced Asymmetric Transformations. Enantiomerically pure (−)-( R)- and (+)-( S)-2,3-Dibromopropan-1-ol and Epibromohydrins. A Study of Dynamic Resolution via the Formation of Diastereoisomeric Esters.
- Authors
Brunetto, Gabriella; Gori, Susanna; Fiaschi, Rita; Napolitano, Elio
- Abstract
( S)-2,3-Dibromopropan-1-ol of high enantiomer excess was obtained by crystallization-induced asymmetric transformations of racemic 2,3-dibromopropan-1-ol esterified with N-([1,1′-biphenyl]-4-ylcarbonyl- L-alanine; in particular, an asymmetric transformation of the first type (involving bromide exchange to equilibrate the diastereoisomeric esters) and an asymmetric transformation of the second type (involving a transesterification of diastereoisomeric esters with excess racemic alcohol) were devised.
- Publication
Helvetica Chimica Acta, 2002, Vol 85, Issue 11, p3785
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/1522-2675(200211)85:11<3785::AID-HLCA3785>3.0.CO;2-A