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- Title
Synthesis and Chemical Transformations of 1-Aryladamantanes.
- Authors
Ivleva, E. A.; Orlinskii, N. S.; Zaborskaya, M. S.; Klimochkin, Yu. N.
- Abstract
1-Aryladamantanes were synthesized, and their transformations in fuming nitric acid were studied. The nitroxylation of the saturated framework are accompanied by the nitration of the aromatic moiety and form 3-(dinitroaryl)adamantan-1-yl nitrates. A number of new polyfunctional compounds were synthesized by the reactions of substituted 3-(dinitroaryl)adamantan-1-yl nitrates with nucleophiles in concentrated sulfuric acid. Due to their polyfunctionality, the compounds obtained can be used as starting substrates in the synthesis of substances with a wide range of biological activity and materials with a complex of valuable properties.
- Subjects
CHEMICAL synthesis; CHEMICAL amplification; NITRIC acid; SULFURIC acid; NITRATION
- Publication
Russian Journal of Organic Chemistry, 2023, Vol 59, Issue 11, p1901
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428023110088