We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Asymmetric oxidation of verbenone ethylene dithioacetal.
- Authors
Timshina, A. V.; Rubtsova, S. A.; Frolova, L. L.; Alekseev, I. N.; Slepukhin, P. A.; Kuchin, A. V.
- Abstract
Asymmetric oxidation of verbenone ethylene dithioacetal with m-chloroperoxybenzoic acid at different substrate-to-oxidant ratios in methylene chloride at −10°C gave previously unknown (1 S,1′ S,2 S,3′ S,5 S)-4,6,6-trimethylspiro[bicyclo[3.1.1]hept-3-ene-2,2′-[1,3]dithiolane] 1′,3′-dioxide, (1 S,2 S,3′ S,5 S)-4,6,6-trimethylspiro[bicyclo[3.1.1]hept-3-ene-2,2′-[1,3]dithiolane] 1′,1′,3′-trioxide, and (1 S,5 S)-4,6,6-trimethylspiro[bicyclo-[3.1.1]hept-3-ene-2,2′-[1,3]dithiolane] 1′,1′,3′,3′-tetraoxide whose structure was determined by X-ray analysis.
- Subjects
DICHLOROMETHANE; ETHYLENE; OXIDATION; PHYSICAL &; theoretical chemistry; TETRAOXYGEN
- Publication
Russian Journal of Organic Chemistry, 2009, Vol 45, Issue 4, p581
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428009040186