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- Title
Cobalt‐Catalyzed Hydrogenation and Deuteration Reactions of Bicyclic Alkenes in an Aqueous Environment.
- Authors
Pounder, Austin; van der Zalm, Joshua; Chen, Aicheng; Tam, William
- Abstract
Herein, we report cobalt‐catalyzed hydrogenation and deuteration reactions of bicyclic alkenes using H2O and D2O as the sole hydrogen and deuterium sources, respectively, employing Zn or Mn as a metal reductant. Lewis‐acid co‐catalysts were found to promote the reaction whilst simultaneously catalyzing transesterification processes. Use of 1 atm of H2 allows for catalytic loading of the metal reductant. In all cases, the reaction operated with high functional‐group tolerance and produced reduced products in high yield.
- Subjects
DEUTERATION; ALKENES; DEUTERIUM oxide; DEUTERIUM; TRANSESTERIFICATION
- Publication
European Journal of Organic Chemistry, 2024, Vol 27, Issue 11, p1
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.202301306