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- Title
ZIF-67-Derived Co/N-Doped Carbon-Functionalized MXene for Enhanced Electrochemical Sensing of Carbendazim.
- Authors
Chen, Shuxian; Zou, Jiamin; Pan, Xiaowei; Zeng, Shaodong; Liu, Yuanjing; Ye, Jianzhi; Lu, Limin; Yang, Shu; Zhan, Guoyan
- Abstract
Herein, ZIF-67-derived Co and N-doped carbon (Co/NC) particle-modified multilayer MXene (MXene@Co/NC) was developed as remarkable electrode material for carbendazim (CBZ) detection. MXene as a substrate provides an excellent conductive framework and plentiful accessibility sites. Co/NC particles embedding in MXene can not only prevent the interlayer stacking of MXene but also contribute a great deal of metal catalytic active sites and finally improve the adsorption and catalytic properties of the composite. Accordingly, the MXene@Co/NC electrode displays excellent electrocatalytic activity toward CBZ oxidation. Experimental parameters such as pH value, accumulation time, MXene@Co/NC modification volume and constituent materials' mass ratios were optimized. Under optimal conditions, the as-prepared sensor based on MXene@Co/NC holds a broad linearity range from 0.01 μM to 45.0 μM with a low limit of detection (LOD) of 3.3 nM (S/N = 3, S means the detection signal, while N represents the noise of the instrument). Moreover, the proposed sensor displays excellent anti-interference ability, superior reproducibility, excellent stability, and successfully achieves actual applications for CBZ detection in a lettuce sample.
- Subjects
CARBENDAZIM; SIGNAL detection; DETECTION limit; DOPING agents (Chemistry); LETTUCE
- Publication
Molecules, 2023, Vol 28, Issue 21, p7347
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules28217347