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- Title
Yttrium-Catalyzed Intramolecular Hydroalkoxylation/Claisen Rearrangement Sequence: Efficient Synthesis of Medium-Sized Lactams.
- Authors
Zhou, Bo; Li, Long; Zhu, Xin ‐ Qi; Yan, Juan ‐ Zhu; Guo, Yi ‐ Lin; Ye, Long ‐ Wu
- Abstract
An efficient yttrium-catalyzed intramolecular hydroalkoxylation/Claisen rearrangement sequence has been achieved, thus enabling facile access to a diverse array of valuable medium-sized lactams. Furthermore, a mechanistic rationale for this novel cascade reaction is well supported by a variety of control experiments.
- Subjects
LACTAMS; CHEMICAL synthesis; YTTRIUM; HOMOGENEOUS catalysis; CLAISEN rearrangement; HETEROCYCLIC compounds; RING formation (Chemistry); CHEMICAL reactions
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 14, p4073
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201700596