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- Title
Reduction Potentials of Tetraaminecopper(II/I) Couples.
- Authors
Comba, Peter; Jakob, Holger
- Abstract
The difference in steric strain between the oxidized and the reduced forms of tetraaminecopper complexes is correlated with the corresponding reduction potentials. The experimentally determined data considered range from −0.54 to −0.04 V ( vs. NHE) in aqueous solution and from −0.35 to −0.08 V ( vs. NHE) in MeCN. The observed and/or computed geometries of the tetraaminecopper(II) complexes are distorted octahedral or square-pyramidal (4 + 2 or 4+1) with (distorted) square-planar CuN4 chromophores (CuIIN = 1.99-2.06 Å; CuO
- Publication
Helvetica Chimica Acta, 1997, Vol 80, Issue 6, p1983
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19970800616