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- Title
Beitrag zur massenspektrometrischen retro-Diels-Alder-Reaktion: 1,2,3,4-Tetrahydrophenanthren. 35. Mitteilung über massenspektrometrische Untersuchungen.
- Authors
Huggenberg, Sonja; Hesse, Manfred
- Abstract
Contribution to the Mass Spectral retro-Diels-Alder Reaction: 1,2,3,4-Tetrahydrophenanthrene [1,4-13C]-1,2,3,4-Tetrahydrophenanthrene (1) was synthesized starting from [1,4-13C]-succinic acid. The mass spectral behavior (EI./MS., 70eV) of 1 is very similar to that of tetraline [2] concerning its loss of ethylene from the molecular ion. Similarly the fragmentation reaction of the synthetic precursors, ketones 7 and 8, seems to partly undergo a carbon rearrangement reaction prior to the elimination of ethylene which is unlike to the behavior of α-tetralone.
- Publication
Helvetica Chimica Acta, 1980, Vol 63, Issue 8, p2295
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19800630819