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- Title
Stereoselectivity in reactions of metal complexes. V. Synthesis of mixed-ligand cobalt(III) complexes with (S)-aspartic-N-monoacetic acid and different amino-acids.
- Authors
Colomb, Gérard; Bernauer, Klaus
- Abstract
The synthesis of mixed-ligand cobalt(III) complexes with ( S)-aspartic-N-monoacetic acid (( S)-AMA) and different amino-acids Na[Co(( S)-AMA)(AA)] (AA = gly, ( R)- and ( S)-ala, val, phe, ser and leu) leads to a mixture of cis-N- and trans-N-isomers. These isomers are formed stereospecifically. VIS., CD.- and NMR.-spectra are reported and a proposal is given for the absolute configuration of all the compounds isolated.
- Publication
Helvetica Chimica Acta, 1977, Vol 60, Issue 2, p459
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19770600217