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- Title
CO-Tolerant Pt-BeO as a Novel Anode Electrocatalyst in Proton Exchange Membrane Fuel Cells.
- Authors
Kyungjung Kwon; Yeojin Jung; Heesuk Ku; Kang Hee Lee; Sookyung Kim; Jeongsoo Sohn; Chanho Pak
- Abstract
Commercialization of proton exchange membrane fuel cells (PEMFCs) requires less expensive catalysts and higher operating voltage. Substantial anodic overvoltage with the usage of reformed hydrogen fuel can be minimized by using CO-tolerant anode catalysts. Carbon-supported Pt-BeO is manufactured so that Pt particles with an average diameter of 4 nm are distributed on a carbon support. XPS analysis shows that a peak value of the binding energy of Be matches that of BeO, and oxygen is bound with Be or carbon. The hydrogen oxidation current of the Pt-BeO catalyst is slightly higher than that of a Pt catalyst. CO stripping voltammetry shows that CO oxidation current peaks at ~0.85 V at Pt, whereas CO is oxidized around 0.75 V at Pt-BeO, which confirms that the desorption of CO is easier in the presence of BeO. Although the state-of-the-art PtRu anode catalyst is dominant as a CO-tolerant hydrogen oxidation catalyst, this study of Be-based CO-tolerant material can widen the choice of PEMFC anode catalyst.
- Subjects
PROTON exchange membrane fuel cells; BERYLLIUM oxide; ANODES
- Publication
Catalysts (2073-4344), 2016, Vol 6, Issue 5, p68
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal6050068