We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Synthesis and Structural Characterization of Some New Magnesium Formamidinates.
- Authors
Cole, Marcus L.; Junk, Peter C.
- Abstract
[Mg(Form)2(THF)] [Form = bis(2,6-dimethylphenyl)- formamidinate (XylForm) (1), bis(2,6-diethylphenyl)formamidinate, (EtForm) (2), bis(2,6-diisopropylphenyl)formamidinate (DippForm) (3)] are conveniently synthesized by treating bis(2,6-dimethylphenyl)- formamidine, bis(2,6-diethylphenyl)formamidine, or bis(2,6-diisopropylphenyl) formamidine, respectively, with half an equivalent of dibut- ylmagnesium in THF. Compounds 1-3 are mononuclear species in the solid state with five coordinate central metal atoms. The 1H NMR chemical shift of the formamidinate formyl proton exhibits a correlation with ligand sterics wherein increasing bulk leads to a shift to higher field.
- Subjects
CHEMICAL synthesis; MAGNESIUM; FORMAMIDINES; ORGANOMAGNESIUM compounds; LIGANDS (Chemistry)
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2015, Vol 641, Issue 15, p2624
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201500659