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- Title
Nanodiamond Supported Ultra-Small Palladium Nanoparticles as an Efficient Catalyst for Suzuki Cross-Coupling Reactions.
- Authors
Pocklanová, Radka; Warkad, Indrajeet R.; Prucek, Robert; Balzerová, Anna; Panáček, Aleš; Kadam, Ravishankar G.; Kvítek, Libor; Gawande, Manoj B.
- Abstract
A nanocatalyst comprising ultra-small palladium nanoparticles supported on nanodiamonds (ultra-small Pd/rNDs) was fabricated via a reduction of palladium (II) salt on oxidized nanodiamond. The prepared catalyst was characterized using XRD, XPS, ICP-MS, AAS, and TEM/HRTEM techniques, including STEM-EDS chemical mapping, which revealed that the modified material is a combination of reduced nanodiamond decorated with palladium nanoparticles. The as-prepared and well-characterized ultra-small Pd supported on rNDs displayed superb catalytic activity for Suzuki–Miyaura cross-coupling reactions at low temperature without any toxic solvents, to obtain the respective products in good-to-excellent yields (75–98%). The catalyst was easily separated from the reaction solution and was reused four times without loss of catalytic activity or chemical stability.
- Subjects
SUZUKI reaction; PALLADIUM; NANODIAMONDS; CHEMICAL stability; CATALYTIC activity; CATALYSTS
- Publication
Catalysts (2073-4344), 2024, Vol 14, Issue 1, p53
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal14010053