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- Title
Mechano-Morphological Characterization of Polyethylene-Glycol Based Polyurethane Microgel.
- Authors
Arzumand, Ayesha; Srinivas, Shruti; Yuan, Yuan; Zhou, Chi; Sarkar, Debanjan
- Abstract
Segmental polyurethanes (PU) with hydrophilic segments form colloidal dispersions which are ultimately arrested into gel-like structure in aqueous continuous phase owing to the differential interactions between polymer and solvent. These structural states of amphiphilic PUs evolve hierarchically, but the structure-function correlation between PU colloidal dispersion and gels is not clear. Here, this correlation is defined from the mechanomorphology of hydrophilic polyethylene glycol based PU which forms dispersions and finally transforms into gel-structure. Morphological and rheological analyses show that PU with comparable hydrophilic and hydrophobic content forms attractive colloids with self-similar fractal microstructures whereas PU with increased hydrophilic character forms space-filling colloids without any defined organization. Furthermore, colloidal dispersions are densified under shear or gravity to form gel where gel mechanics is defined by colloidal particle organization and the morphology is dependent on gelation mode. This stepwise organization of PU colloidal particles into microgel can independently control microgel mechanics and morphology.
- Subjects
MECHANICAL properties of polymers; COLLOIDS; POLYURETHANES; POLYETHYLENE; MICROGELS
- Publication
Macromolecular Materials & Engineering, 2016, Vol 301, Issue 10, p1158
- ISSN
1438-7492
- Publication type
Article
- DOI
10.1002/mame.201600186