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- Title
The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines.
- Authors
Kalogirou, Andreas S.; Koutentis, Panayiotis A.
- Abstract
N-Aryl-S,S-dimethylsulfimides 3 (Ar = 4-NO2C6H4), 4 (Ar = Ph) and 5 (Ar = 4- Tol) react with Appel salt 1 to give the corresponding N-aryl-(4-chloro-5H-1,2,3- dithiazolylidene)benzenamines 8 (Ar = 4-NO2C6H4), 9 (Ar = Ph) and 10 (Ar = 4-Tol) in 84, 94 and 87% yields, respectively. The reaction proceeds in the absence of base and a proposed reaction mechanism is given.
- Subjects
CHLORIDES; BIOSYNTHESIS; AROMATIC amines; CHEMICAL reactions; REACTION mechanisms (Chemistry)
- Publication
Molecules, 2009, Vol 14, Issue 7, p2356
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules14072356