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Enantioconvergent Cross‐Couplings of Alkyl Electrophiles: The Catalytic Asymmetric Synthesis of Organosilanes.
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- Angewandte Chemie, 2019, v. 131, n. 11, p. 3609, doi. 10.1002/ange.201814208
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Nickel‐Catalyzed Enantioconvergent Borylation of Racemic Secondary Benzylic Electrophiles.
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- Angewandte Chemie, 2018, v. 130, n. 44, p. 14737, doi. 10.1002/ange.201806015
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Control of Vicinal Stereocenters through Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling.
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- Angewandte Chemie, 2017, v. 129, n. 21, p. 5915, doi. 10.1002/ange.201702402
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Nickel‐Catalyzed Enantioconvergent Borylation of Racemic Secondary Benzylic Electrophiles.
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- Angewandte Chemie International Edition, 2018, v. 57, n. 44, p. 14529, doi. 10.1002/anie.201806015
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Control of Vicinal Stereocenters through Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling.
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- Angewandte Chemie International Edition, 2017, v. 56, n. 21, p. 5821, doi. 10.1002/anie.201702402
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Nickel-Catalyzed Alkyl-Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds having a Perfluoroalkyl Substituent.
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- Angewandte Chemie International Edition, 2015, v. 54, n. 31, p. 9047, doi. 10.1002/anie.201503297
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Biphenyl-Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes.
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- Angewandte Chemie International Edition, 2014, v. 53, n. 48, p. 13183, doi. 10.1002/anie.201405854
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Nickel-Catalyzed Alkyl-Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds having a Perfluoroalkyl Substituent.
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- Angewandte Chemie, 2015, v. 127, n. 31, p. 9175, doi. 10.1002/ange.201503297
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Biphenyl-Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes.
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- Angewandte Chemie, 2014, v. 126, n. 48, p. 13399, doi. 10.1002/ange.201405854
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Transition-Metal-Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper-Catalyzed Couplings of Carbazoles.
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- Angewandte Chemie, 2013, v. 125, n. 19, p. 5233, doi. 10.1002/ange.201301202
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Catalytic Asymmetric CN Bond Formation: Phosphine-Catalyzed Intra- and Intermolecular γ-Addition of Nitrogen Nucleophiles to Allenoates and Alkynoates.
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- Angewandte Chemie, 2013, v. 125, n. 9, p. 2585, doi. 10.1002/ange.201208957
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Alkyl-Alkyl Suzuki Cross-Coupling of Unactivated Secondary Alkyl Chlorides.
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- Angewandte Chemie, 2010, v. 122, n. 37, p. 6826, doi. 10.1002/ange.201003272
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A Convenient and General Method for Pd-Catalyzed Suzuki Cross-Couplings of Aryl Chlorides and Arylboronic Acids.
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- Angewandte Chemie International Edition, 1998, v. 37, n. 24, p. 3387, doi. 10.1002/(SICI)1521-3773(19981231)37:24<3387::AID-ANIE3387>3.0.CO;2-P
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Defining the Conformation of Lewis Acid/Lewis Base Complex: Crystallographic Evidence for Simultaneous σ and π Donation by a Carbonyl Group to a Divalent Boron Lewis Acid.
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- Angewandte Chemie International Edition, 1997, v. 36, n. 3, p. 267, doi. 10.1002/anie.199702671
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Iron‐Catalyzed Reductive Cross‐Coupling of Alkyl Electrophiles with Olefins.
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- Angewandte Chemie, 2023, v. 135, n. 34, p. 1, doi. 10.1002/ange.202306663
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Iron‐Catalyzed Reductive Cross‐Coupling of Alkyl Electrophiles with Olefins.
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- Angewandte Chemie International Edition, 2023, v. 62, n. 34, p. 1, doi. 10.1002/anie.202306663
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Enantioconvergent Cross‐Couplings of Alkyl Electrophiles: The Catalytic Asymmetric Synthesis of Organosilanes.
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- Angewandte Chemie International Edition, 2019, v. 58, n. 11, p. 3571, doi. 10.1002/anie.201814208
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Stereoselective Phosphine-Catalyzed Synthesis of Highly Functionalized Diquinanes.
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- Angewandte Chemie, 2010, v. 122, n. 1, p. 165, doi. 10.1002/ange.200905125
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Catalytic Asymmetric Cross-Couplings of Racemic α-Bromoketones with Arylzinc Reagents.
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- Angewandte Chemie, 2009, v. 121, n. 1, p. 160, doi. 10.1002/ange.200804888
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Nickel-Catalyzed Negishi Cross-Couplings of Secondary Nucleophiles with Secondary Propargylic Electrophiles at Room Temperature.
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- Angewandte Chemie, 2008, v. 120, n. 48, p. 9474, doi. 10.1002/ange.200802784
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Synthesis of Functionalized Cyclopentenes through Catalytic Asymmetric [3+2] Cycloadditions of Allenes with EnonesWe thank Luke Firmansjah and Dr. Peter Mueller for assistance (X-ray crystallography) and the Jamison group for a sample of (R)-nmdpp. Support has been provided by the NIH (National Institute of General Medical Sciences: R01-GM57034; National Cancer Institute: training grant CA009112), Merck Research Laboratories, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592.
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- Angewandte Chemie, 2006, v. 118, n. 9, p. 1454, doi. 10.1002/ange.200503312
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A Versatile Method for Suzuki Cross-Coupling Reactions of Nitrogen HeterocyclesWe thank Frontier Scientific for boronic acids and Johnson Matthey for [Pd2(dba)3]. Financial support was provided by the National Institutes of Health (National Institute of General Medical Sciences, R01-GM62871), Merck Research Laboratories, Novartis, Sankyo-Agro Co. Ltd. (N.K.), and Novartis Stiftung (M.P.). Funding for the MIT Department of Chemistry Instrumentation Facility was furnished in part by the National Science Foundation (CHE-9808061 and DBI-9729592).
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- Angewandte Chemie, 2006, v. 118, n. 8, p. 1304, doi. 10.1002/ange.200503479
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Catalytic Asymmetric Couplings of Ketenes with Aldehydes To Generate Enol EstersSupport was provided by the NIH (NIGMS, GM57034), the Deutsche Forschungsgemeinschaft (postdoctoral fellowship to C.S.), Merck Research Laboratories, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility was furnished in part by the National Science Foundation (CHE-9808061 and DBI-9729592).
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- Angewandte Chemie, 2005, v. 117, n. 29, p. 4682, doi. 10.1002/ange.200501434
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Nucleophile-Catalyzed Asymmetric Acylations of Silyl Ketene Imines: Application to the Enantioselective Synthesis of Verapamil.
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- Angewandte Chemie, 2005, v. 117, n. 6, p. 971, doi. 10.1002/ange.200461886
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Asymmetric Synthesis of Highly Substituted β-Lactones by Nucleophile-Catalyzed [2+2] Cycloadditions of Disubstituted Ketenes with AldehydesWe thank Ivory D. Hills for X-ray crystallographic studies. Support has been provided by the National Institutes of Health (National Institute of General Medical Sciences: R01-GM57034; National Cancer Institute: training grant CA009112), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592.
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- Angewandte Chemie, 2004, v. 116, n. 46, p. 6518, doi. 10.1002/ange.200460698
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A Straightforward and Mild Synthesis of Functionalized 3-AlkynoatesSupport has been provided by the National Institutes of Health (National Institute of General Medical Sciences, R01-GM066960), the Spanish Ministry of Education, Culture, and Sports (postdoctoral fellowship to A.S.), Merck Research Laboratories, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592.
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- Angewandte Chemie, 2004, v. 116, n. 27, p. 3664
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Toward an Improved Understanding of the Unusual Reactivity of Pd<sup>0</sup>/Trialkylphosphane Catalysts in Cross-Couplings of Alkyl Electrophiles: Quantifying the Factors That Determine the Rate of Oxidative Addition ( Support has been provided by...
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- Angewandte Chemie, 2003, v. 115, n. 46, p. 5927, doi. 10.1002/ange.200352858
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Ligands for Palladium-Catalyzed Cross-Couplings of Alkyl Halides: Use of an Alkyldiaminophosphane Expands the Scope of the Stille Reaction ( We thank Johnson Matthey for supplying palladium compounds. Support has been provided by the National Institutes of Health (National Institute of General Medical Sciences, R01-GM62871), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592. )
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- Angewandte Chemie, 2003, v. 115, n. 41, p. 5233, doi. 10.1002/ange.200352668
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Catalytic Enantioselective Synthesis of β-Lactams: Intramolecular Kinugasa Reactions and Interception of an Intermediate in the Reaction Cascade ( Support has been provided by the National Institutes of Health (National Institute of General Medical Sciences, R01-GM066960), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592. We thank Ivory D. Hills for an X-ray crystallographic study. )
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- Angewandte Chemie, 2003, v. 115, n. 34, p. 4216, doi. 10.1002/ange.200352103
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Catalytic Enantioselective Synthesis of Oxindoles and Benzofuranones That Bear a Quaternary Stereocenter ( We thank Dr. J. Craig Ruble for preliminary experiments. Support has been provided by the American Chemical Society (Organic Division Fellowship to I.D.H., sponsored by Abbott Laboratories), the National Institutes of Health (National Institute of General Medical Sciences, R01-GM57034), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592. )
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- Angewandte Chemie, 2003, v. 115, n. 33, p. 4051, doi. 10.1002/ange.200351666
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Titelbild: Catalytic Enantioselective Synthesis of Oxindoles and Benzofuranones That Bear a Quaternary Stereocenter (Angew. Chem. 33/2003).
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- Angewandte Chemie, 2003, v. 115, n. 33, p. 3969, doi. 10.1002/ange.200390584
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Enantioselective Synthesis of Protected Amines by the Catalytic Asymmetric Addition of Hydrazoic Acid to Ketenes.
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- Angewandte Chemie International Edition, 2007, v. 46, n. 23, p. 4367, doi. 10.1002/anie.200700697
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Hiyama Reactions of Activated and Unactivated Secondary Alkyl Halides Catalyzed by a Nickel/Norephedrine Complex.
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- Angewandte Chemie International Edition, 2007, v. 46, n. 19, p. 3556, doi. 10.1002/anie.200700440
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Catalytic Asymmetric Synthesis of Tertiary Alkyl Chlorides.
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- Angewandte Chemie International Edition, 2007, v. 46, n. 6, p. 977, doi. 10.1002/anie.200604312
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- Article
Synthesis of Functionalized Cyclopentenes through Catalytic Asymmetric [3+2] Cycloadditions of Allenes with EnonesWe thank Luke Firmansjah and Dr. Peter Mueller for assistance (X-ray crystallography) and the Jamison group for a sample of (R)-nmdpp. Support has been provided by the NIH (National Institute of General Medical Sciences: R01-GM57034; National Cancer Institute: training grant CA009112), Merck Research Laboratories, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592.
- Published in:
- Angewandte Chemie International Edition, 2006, v. 45, n. 9, p. 1426, doi. 10.1002/anie.200503312
- By:
- Publication type:
- Article
A Versatile Method for Suzuki Cross-Coupling Reactions of Nitrogen HeterocyclesWe thank Frontier Scientific for boronic acids and Johnson Matthey for [Pd2(dba)3]. Financial support was provided by the National Institutes of Health (National Institute of General Medical Sciences, R01-GM62871), Merck Research Laboratories, Novartis, Sankyo-Agro Co. Ltd. (N.K.), and Novartis Stiftung (M.P.). Funding for the MIT Department of Chemistry Instrumentation Facility was furnished in part by the National Science Foundation (CHE-9808061 and DBI-9729592).
- Published in:
- Angewandte Chemie International Edition, 2006, v. 45, n. 8, p. 1282, doi. 10.1002/anie.200503479
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- Publication type:
- Article
Catalytic Asymmetric Couplings of Ketenes with Aldehydes To Generate Enol EstersSupport was provided by the NIH (NIGMS, GM57034), the Deutsche Forschungsgemeinschaft (postdoctoral fellowship to C.S.), Merck Research Laboratories, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility was furnished in part by the National Science Foundation (CHE-9808061 and DBI-9729592).
- Published in:
- Angewandte Chemie International Edition, 2005, v. 44, n. 29, p. 4606, doi. 10.1002/anie.200501434
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- Publication type:
- Article
Nucleophile-Catalyzed Asymmetric Acylations of Silyl Ketene Imines: Application to the Enantioselective Synthesis of VerapamilSupport has been provided by the National Institutes of Health (National Institute of General Medical Sciences: R01-GM57034; National Cancer Institute: training grant CA009112), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592.
- Published in:
- Angewandte Chemie International Edition, 2005, v. 44, n. 6, p. 949, doi. 10.1002/anie.200461886
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- Publication type:
- Article
Asymmetric Synthesis of Highly Substituted β-Lactones by Nucleophile-Catalyzed [2+2] Cycloadditions of Disubstituted Ketenes with AldehydesWe thank Ivory D. Hills for X-ray crystallographic studies. Support has been provided by the National Institutes of Health (National Institute of General Medical Sciences: R01-GM57034; National Cancer Institute: training grant CA009112), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592.
- Published in:
- Angewandte Chemie International Edition, 2004, v. 43, n. 46, p. 6358, doi. 10.1002/anie.200460698
- By:
- Publication type:
- Article
A Straightforward and Mild Synthesis of Functionalized 3-Alkynoates.
- Published in:
- Angewandte Chemie International Edition, 2004, v. 43, n. 27, p. 3580, doi. 10.1002/anie.200454070
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- Publication type:
- Article
Toward an Improved Understanding of the Unusual Reactivity of Pd<sup>0</sup>/Trialkylphosphane Catalysts in Cross-Couplings of Alkyl Electrophiles: Quantifying the Factors That Determine the Rate of Oxidative Addition ( Support has been provided by the National Institutes of Health (National Institute of General Medical Sciences, R01-GM62871 to G.C.F. and R01-GM57034 supplement to I.D.H.), the American Chemical Society (Organic Division Fellowship to I.D.H., sponsored by Abbott Laboratories), the Natural Sciences and Engineering Research Council of Canada (Postdoctoral Fellowship to M.R.N.), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592. We thank Johnson Matthey for supplying palladium compounds. )
- Published in:
- Angewandte Chemie International Edition, 2003, v. 42, n. 46, p. 5749, doi. 10.1002/anie.200352858
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- Publication type:
- Article
Ligands for Palladium-Catalyzed Cross-Couplings of Alkyl Halides: Use of an Alkyldiaminophosphane Expands the Scope of the Stille Reaction ( We thank Johnson Matthey for supplying palladium compounds. Support has been provided by the National Institutes of Health (National Institute of General Medical Sciences, R01-GM62871), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592. )
- Published in:
- Angewandte Chemie International Edition, 2003, v. 42, n. 41, p. 5079, doi. 10.1002/anie.200352668
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- Publication type:
- Article
Catalytic Enantioselective Synthesis of β-Lactams: Intramolecular Kinugasa Reactions and Interception of an Intermediate in the Reaction Cascade ( Support has been provided by the National Institutes of Health (National Institute of General Medical Sciences, R01-GM066960), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592. We thank Ivory D. Hills for an X-ray crystallographic study. )
- Published in:
- Angewandte Chemie International Edition, 2003, v. 42, n. 34, p. 4082, doi. 10.1002/anie.200352103
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- Publication type:
- Article
Catalytic Enantioselective Synthesis of Oxindoles and Benzofuranones That Bear a Quaternary Stereocenter ( We thank Dr. J. Craig Ruble for preliminary experiments. Support has been provided by the American Chemical Society (Organic Division Fellowship to I.D.H., sponsored by Abbott Laboratories), the National Institutes of Health (National Institute of General Medical Sciences, R01-GM57034), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592. )
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- Angewandte Chemie International Edition, 2003, v. 42, n. 33, p. 3921, doi. 10.1002/anie.200351666
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Cover Picture: Catalytic Enantioselective Synthesis of Oxindoles and Benzofuranones That Bear a Quaternary Stereocenter (Angew. Chem. Int. Ed. 33/2003).
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- Angewandte Chemie International Edition, 2003, v. 42, n. 33, p. 3839, doi. 10.1002/anie.200390555
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Palladium-Catalyzed Coupling Reactions of Aryl Chlorides.
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- Angewandte Chemie International Edition, 2002, v. 41, n. 22, p. 4176, doi. 10.1002/1521-3773(20021115)41:22<4176::AID-ANIE4176>3.0.CO;2-U
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Application of a New Family of P,N Ligands to the Highly Enantioselective Hydrosilylation of Aryl Alkyl and Dialkyl Ketones.
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- Angewandte Chemie International Edition, 2002, v. 41, n. 20, p. 3892, doi. 10.1002/1521-3773(20021018)41:20<3892::AID-ANIE3892>3.0.CO;2-A
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Suzuki Cross-Couplings of Alkyl Tosylates that Possess β Hydrogen Atoms: Synthetic and Mechanistic Studies.
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- Angewandte Chemie International Edition, 2002, v. 41, n. 20, p. 3910, doi. 10.1002/1521-3773(20021018)41:20<3910::AID-ANIE3910>3.0.CO;2-W
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A Method for Palladium-Catalyzed Cross-Couplings of Simple Alkyl Chlorides: Suzuki Reactions Catalyzed by [Pd.
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- Angewandte Chemie International Edition, 2002, v. 41, n. 11, p. 1945, doi. 10.1002/1521-3773(20020603)41:11<1945::AID-ANIE1945>3.0.CO;2-7
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A Novel Rhodium-Catalyzed Reduction-Oxidation Process: Reaction of 4-Alkynals with Phenol to Provide cis-4-Alkenoates.
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- Angewandte Chemie International Edition, 2002, v. 41, n. 9, p. 1607, doi. 10.1002/1521-3773(20020503)41:9<1607::AID-ANIE1607>3.0.CO;2-Q
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