We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Catalytic effect analysis of metallic additives on light crude oil by TG and DSC tests.
- Authors
Li, Yi-Bo; Zhao, Jin-Zhou; Pu, Wan-Fen; Jia, Hu; Peng, Huan; Zhong, Dong; Wang, Sheng-Kui
- Abstract
This research aimed at the investigation of the effect of different metallic additive on the combustion and kinetic behavior of crude oil. For this purpose, the thermal behavior of the oil-only and oil-metallic salts mixtures were studies by the thermogravimetry (TG)/derivative thermogravimetry and differential scanning calorimetry (DSC) on heating rate at 10 °C min. The result shows that Dagang crude oil exhibited apparent low temperature oxidation (LTO), fuel deposition, and high temperature oxidation processes. With the addition of metallic salts, the LTO process has been shortened and samples added CuSO, CrCl·6HO, and AlCl·6HO achieved a much lower peak temperature than that of oil. Based on the Arrhenius model, metallic additives were proven to have obvious influence on the combustion activation energy. And, by comprehensive analysis of TG/DSC profile and activation energy, ZnSO exhibited a positive influence on light crude oil combustion during the high pressure air injection process.
- Subjects
CATALYTIC activity; ADDITIVES; BIOMASS burning; CHEMICAL kinetics; DIFFERENTIAL scanning calorimetry; MIXTURES; HIGH temperatures
- Publication
Journal of Thermal Analysis & Calorimetry, 2013, Vol 113, Issue 2, p579
- ISSN
1388-6150
- Publication type
Article
- DOI
10.1007/s10973-012-2759-7