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- Title
Graphene Oxide/Polyacrylamide/Aluminum Ion Cross-Linked Carboxymethyl Hemicellulose Nanocomposite Hydrogels with Very Tough and Elastic Properties.
- Authors
Kong, Weiqing; Huang, Danyang; Xu, Guibin; Ren, Junli; Liu, Chuanfu; Zhao, Lihong; Sun, Runcang
- Abstract
Development of high-strength hydrogels has recently attracted ever-increasing attention. In this work, a new design strategy has been proposed to prepare graphene oxide (GO)/polyacrylamide (PAM)/aluminum ion (Al3+)-cross-linked carboxymethyl hemicellulose (Al-CMH) nanocomposite hydrogels with very tough and elastic properties. GO/PAM/Al-CMH hydrogels were synthesized by introducing graphene oxide (GO) into PAM/CMH hydrogel, followed by ionic cross-linking of Al3+. The nanocomposite hydrogels were characterized by means of FTIR, X-ray diffraction (XRD), and scanning electron microscopy/energy-dispersive X-ray analysis (SEM-EDX) along with their swelling and mechanical properties. The maximum compressive strength and the Young's modulus of GO3.5/PAM/Al-CMH0.45 hydrogel achieved values of up to 1.12 and 13.27 MPa, increased by approximately 6488 and 18330 % relative to the PAM hydrogel (0.017 and 0.072 MPa). The as-prepared GO/PAM/Al-CMH nanocomposite hydrogels possess high strength and great elasticity giving them potential in bioengineering and drug-delivery system applications.
- Subjects
HYDROGELS; NANOCOMPOSITE materials; GRAPHENE oxide; POLYACRYLAMIDE; HEMICELLULOSE; ELASTICITY
- Publication
Chemistry - An Asian Journal, 2016, Vol 11, Issue 11, p1697
- ISSN
1861-4728
- Publication type
Article
- DOI
10.1002/asia.201600138