We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Catalytic Enantioselective CH Functionalization of Alcohols by Redox-Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon.
- Authors
Ketcham, John M.; Shin, Inji; Montgomery, T. Patrick; Krische, Michael J.
- Abstract
The use of alcohols and unsaturated reactants for the redox-triggered generation of nucleophile-electrophile pairs represents a broad, new approach to carbonyl addition chemistry. Discrete redox manipulations that are often required for the generation of carbonyl electrophiles and premetalated carbon-centered nucleophiles are thus avoided. Based on this concept, a broad, new family of enantioselective CC coupling reactions that are catalyzed by iridium or ruthenium complexes have been developed, which are summarized in this Minireview.
- Subjects
ALCOHOLS (Chemical class); CARBON compounds spectra; BIOCHEMICAL substrates; NUCLEOPHILES; IRIDIUM; REDOX polymers
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 35, p9142
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201403873