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- Title
Nickel-Catalysed Hydroalkoxylation Reaction of 1,3-Butadiene: Ligand Controlled Selectivity for the Efficient and Atom-Economical Synthesis of Alkylbutenyl Ethers.
- Authors
Bigot, Sandra; El Alami, Mohammed Samir Ibn; Mifleur, Alexis; Castanet, Yves; Suisse, Isabelle; Mortreux, André; Sauthier, Mathieu
- Abstract
The nickel‐catalysed hydroalkoxylation of butadiene is promoted by a nickel(0)/dppb catalyst (dppb=1,4‐bis(diphenylphosphino)butane; see scheme). By following this new synthetic procedure, alkylbutenyl ethers are readily obtained from an alcohol and 1,3‐butadiene with exclusion of dimerisation and telomerisation products.
- Subjects
ETHOXYLATION; BENZYL alcohol; PHOSPHINES; PHOSPHORUS compounds; NICKEL
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 30, p9785
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201300633