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- Title
Spin-crossover phenomena of the assembled iron complexes by enclathrating an organic molecule.
- Authors
Nakashima, S.; Morita, T.; Yamada, K.; Inoue, K.
- Abstract
Assembled complex, Fe(bpa)2(NCX)2 (bpa=1,2-bis(4-pyridyl)ethane; X=S, Se, BH3) enclathrated diphenylmethane. The skeletons were interpenetrating structures for NCS and NCSe complexes, while 2D grid structure was obtained for NCBH3 complex. The assembled iron complexes showed spin-crossover phenomena by enclathrating diphenylmethane. The ratio of spin transition and the transition temperature depended on the assembled structure.
- Subjects
TRANSITION temperature; IRON; CLATHRATE compounds; SELENIUM; MOSSBAUER spectroscopy; SPECTRUM analysis
- Publication
Hyperfine Interactions, 2005, Vol 166, Issue 1-4, p469
- ISSN
0304-3843
- Publication type
Article
- DOI
10.1007/s10751-006-9310-9