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- Title
TOTAL SYNTHESIS OF GERMANIUM (II) AND GERMANIUM(IV) DERIVATIVES FROM GERMANIUM (in French).
- Authors
Rivière, P.; Castel, A.; Satge, J.; Abdennadher, C.
- Abstract
Bivalent germanium compounds GeX2 and PhGeX where X=F, Cl, were generated by direct reaction between germanium powder and corresponding mercuric halides e.g. HgX2 and PhHgX. Difluorogermylene was isolated by sublimation, other halogermylenes (GeCl2 and PhGeCl) were characterized by trapping cycloaddition or insertion reactions. Mass spectroscopic characterization of some reaction intermediates suggests successive S.E.T. reactions and the transient formation of germyne. Characterisation of the insertion products or cycloadducts, when these are formed in very low yields, was made by analytic comparisons (CPV, RMN and mass spectroscopy) with authentic samples synthetized by other ways.
- Publication
Main Group Metal Chemistry, 1994, Vol 17, Issue 7, p491
- ISSN
0792-1241
- Publication type
Article