We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Carboranylphosphinic Acids: A New Class of Purely Inorganic Ligands.
- Authors
Oleshkevich, Elena; Teixidor, Francesc; Choquesillo‐Lazarte, Duane; Sillanpää, Reijo; Viñas, Clara
- Abstract
Purely inorganic carboranyl phosphinates were prepared, and the influence of the cluster on the reactivity of the phosphinate group was studied. Electron-withdrawal by the carboranyl carbon atoms, combined with space-filling efficiency and enhanced aromaticity of the cluster cage, renders the phosphorus more difficult to oxidize. This enables carboranyl phosphinates to survive harsh oxidizing conditions, a property which is uncommon in organic phosphinates.
- Subjects
PHOSPHINIC acid; LIGANDS (Chemistry); INORGANIC chemistry; REACTIVITY (Chemistry); AROMATICITY
- Publication
Chemistry - A European Journal, 2016, Vol 22, Issue 11, p3665
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201504408