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- Title
Synthesis and Spectroscopic Characterization of New Ligand and Its Pd(II), Cu(II) Metal Complexes.
- Authors
Sadiq, Hamsa T.; Al-Karkhi, Isam H. T.; Jassim, Ayad H.
- Abstract
A novel Schiff base ligand containing nitrogen and sulfur donor atoms was synthesized by condensing thioamide (TA) with imidothioic acid (IT) to form 1, 4 dithiane-2, 3-diamine (TAIT). Metal complexes of this ligand were prepared using Cu (II) chloride dihydrates and Pd (III) chloride. These complexes have been characterized using various physico-chemical and spectroscopic techniques. Based on physico-chemical and spectroscopic analyses, the structure of Cu (II) complex is expected to be octahedral, while Pd (II) complex is proposed to be square planner geometry. Schiff base and its metal complexes were expected to show strong bioactivity against microbes and cancer cells.
- Subjects
SCHIFF bases; METAL complexes; LIGANDS (Chemistry); THIOAMIDES; SPECTRUM analysis
- Publication
Orbital: The Electronic Journal of Chemistry, 2013, Vol 5, Issue 2, p84
- ISSN
1984-6428
- Publication type
Article