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- Title
One-Step Synthesis of the Vicinal Dinitroguaianolides Achillin and Grossmisin.
- Authors
Alebastrov, O. V.; Raldugin, V. A.; Bagryanskaya, I. Yu.; Gatilov, Yu. V.; Shakirov, M. M.; Kulyyasov, A. T.; Adekenov, S. M.
- Abstract
1,10-Dihydro-1α,10α-dinitrogrossmisin was synthesized by bubbling gaseous nitrosyl chloride through a chloroform solution of the guaianolide grossmisin. The molecular structure was determined by X-ray. It was found that the formation of similar dinitrates is accelerated by using NOCl containing nitrogen dioxide.
- Subjects
NITROGEN oxychlorides; CHLORINE compounds; MOLECULAR structure; NITROGEN dioxide; NITROSYL chloride; NITROGEN compounds
- Publication
Chemistry of Natural Compounds, 2003, Vol 39, Issue 4, p362
- ISSN
0009-3130
- Publication type
Article
- DOI
10.1023/B:CONC.0000003417.79920.8d