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- Title
Composition and reactivity of volatile organic compounds in the South Coast Air Basin and San Joaquin Valley of California.
- Authors
Liu, Shang; Barletta, Barbara; Hornbrook, Rebecca S.; Fried, Alan; Peischl, Jeff; Meinardi, Simone; Coggon, Matthew; Lamplugh, Aaron; Gilman, Jessica B.; Gkatzelis, Georgios I.; Warneke, Carsten; Apel, Eric C.; Hills, Alan J.; Bourgeois, Ilann; Walega, James; Weibring, Petter; Richter, Dirk; Kuwayama, Toshihiro; FitzGibbon, Michael; Blake, Donald
- Abstract
Comprehensive aircraft measurements of volatile organic compounds (VOCs) covering the South Coast Air Basin (SoCAB) and San Joaquin Valley (SJV) of California were obtained in the summer of 2019. Combined with the CO, CH 4 , and NO x data, the total calculated gas-phase hydroxyl radical reactivity (cOHR TOTAL) was quantified to be 6.1 and 4.6 s -1 for the SoCAB and SJV, respectively. VOCs accounted for ∼ 60 %–70 % of the cOHR TOTAL in both basins. In particular, oxygenated VOCs (OVOCs) contributed >60 % of the cOHR of total VOCs (cOHR VOC) and the total observed VOC mixing ratio. Primary biogenic VOCs (BVOCs) represented a minor fraction (<2 %) of the total VOC mixing ratio but accounted for 21 % and 6 % of the cOHR VOC in the SoCAB and SJV, respectively. Furthermore, the contribution of BVOCs to the cOHR VOC increased with increasing cOHR VOC in the SoCAB, suggesting that BVOCs were important ozone precursors during high ozone episodes. Spatially, the trace gases were heterogeneously distributed in the SoCAB, with their mixing ratios and cOHR being significantly greater over the inland regions than the coast, while their levels were more evenly distributed in SJV. The results highlight that a better grasp of the emission rates and sources of OVOCs and BVOCs is essential for a predictive understanding of the ozone abundance and distribution in California.
- Subjects
CALIFORNIA; VOLATILE organic compounds; TRACE gases; HYDROXYL group; COASTS; BIOGENIC amines
- Publication
Atmospheric Chemistry & Physics, 2022, Vol 22, Issue 16, p10937
- ISSN
1680-7316
- Publication type
Article
- DOI
10.5194/acp-22-10937-2022