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- Title
Expansion of the composition library for chemodiversity of hardwood extractives at molecular level by ultrahigh-resolution mass spectrometry.
- Authors
Hu, Wenya; Pan, Qiong; Wang, Yinghao; Li, Dongze; Zhang, Yanfen; Nie, Honggang; Han, Yehua; Hsu, Chang Samuel
- Abstract
To enhance the characterization of wood extractives at molecular level, a detailed ultrahigh-resolution mass spectrometry (UHRMS)–based analytical methodology was developed in this work. The analytical strategies, including selection of compatible solvent for extraction, evaluation of ionization solvent for effective electrospray ionization, and multi-dimensional data analysis, were established to ensure a comprehensive characterization of complex compositions in wood extractives. Extraction capability of seven solvents with varied polarities was examined by a standard reference material of hardwood biomass and evaluated based on thousands of compounds which were much more than those discovered before. With a variety of data-processing approaches, including compound type distribution, double bond equivalent versus carbon number plot, and van Krevelen diagram, the chemodiversity of the extractives was fully explored from different perspectives. This work greatly expanded the compound library of wood extractives and could also provide guidance for the integrated composition analysis of other biomass materials.
- Subjects
MASS spectrometry; HARDWOODS; WOOD; SOLVENT extraction; WOOD chemistry; DOUBLE bonds
- Publication
Analytical & Bioanalytical Chemistry, 2022, Vol 414, Issue 8, p2687
- ISSN
1618-2642
- Publication type
Article
- DOI
10.1007/s00216-022-03909-8