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- Title
Formation of MPd<sub>3 + x</sub> (M = Gd, Np) by the reaction of MN with Pd and chlorination of MPd<sub>3 + x</sub> using cadmium chloride.
- Authors
Hayashi, Hirokazu; Shibata, Hiroki; Sato, Takumi; Otobe, Haruyoshi
- Abstract
The formation of MPd3 + x (M = Gd, Np) by the reaction of MN with Pd at 1323 K in Ar gas flow was observed. Cubic AuCu3-type GdPd3.3 (a = 0.4081 ± 0.0001 nm) and NpPd3 (a = 0.4081 ± 0.0001 nm) were identified, respectively. The product obtained from the reaction of NpN with Pd contained additional phases, including the hexagonal TiNi3-type NpPd3. Chlorination of the MPd3 + x (M = Gd, Np) samples was accomplished by the solid-state reaction using cadmium chloride at 673 K in a dynamic vacuum.
- Subjects
CADMIUM chloride; CHLORINATION; PLATINUM group; GAS flow; WATER chlorination
- Publication
Journal of Radioanalytical & Nuclear Chemistry, 2023, Vol 332, Issue 2, p503
- ISSN
0236-5731
- Publication type
Article
- DOI
10.1007/s10967-023-08760-4