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- Title
Synthesis and Transformations of Aryl-Substituted Alkenes of the Adamantane Series.
- Authors
Savel’eva, S. A.; Leonova, M. V.; Baimuratov, M. R.; Klimochkin, Yu. N.
- Abstract
Aryl-substituted alkenes of the adamantane series, 1-[(Z,E)-3-phenylprop-2-en-1-yl]adamantane and 1-[(Z)-3-phenylprop-1-en-1-yl]adamantane, have been synthesized by the Wittig reaction. Their allylic bromination involves two concurrent reactions, radical substitution and raical addition. The different chemical behaviors of the aryl-substituted alkenes have been demonstrated in the Ritter reaction. Depending on the alkene structure and acid catalyst nature, the products are secondary amides, sulfonic acid derivatives, and homoadamantane γ-sultone.
- Subjects
ALKENE synthesis; HYDROCARBON synthesis; ADAMANTANE; CYCLOALKANES; WITTIG reaction
- Publication
Russian Journal of Organic Chemistry, 2018, Vol 54, Issue 7, p996
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428018070047