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- Title
Catalytic Aerobic Oxidation of Arylhydrazides with Iron Phthalocyanine.
- Authors
Hashimoto, Takuma; Hirose, Daisuke; Taniguchi, Tsuyoshi
- Abstract
A convenient method for the synthesis of 2-arylazocarboxylates from 2-arylhydrazinecarboxylates by aerobic oxidation with iron phthalocyanine is described. The reaction is applicable to oxidative activation of 1-acyl-2-phenylhydrazines. Some preliminary experiments suggest Michaelis-Menten kinetics and participation of radical species in the reaction mechanism.
- Subjects
AZO compounds; OXIDATION; AZO compound synthesis; PHTHALOCYANINE synthesis; PHENYLHYDRAZINE; MICHAELIS-Menten equation
- Publication
Advanced Synthesis & Catalysis, 2015, Vol 357, Issue 14/15, p3346
- ISSN
1615-4150
- Publication type
Other
- DOI
10.1002/adsc.201500459