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- Title
Theoretical Study and Analysis of CsSnX 3 (X = Cl, Br, I) All-Inorganic Perovskite Solar Cells with Different X-Site Elements.
- Authors
Yuan, Shiyu; Li, Zhenzhen; Wang, Yitong; Zhao, Hang
- Abstract
In this research, SCAPS-1D simulation software (Version: 3.3.10) was employed to enhance the efficiency of CsSnX3 (X = Cl, Br, I) all-inorganic perovskite solar cells. By fine-tuning essential parameters like the work function of the conductive glass, the back contact point, defect density, and the thickness of the light absorption layer, we effectively simulated the optimal performance of CsSnX3 (X = Cl, Br, I) all-inorganic perovskite solar cells under identical conditions. The effects of different X-site elements on the overall performance of the device were also explored. The theoretical photoelectric conversion efficiency of the device gradually increases with the successive substitution of halogen elements (Cl, Br, I), reaching 6.09%, 17.02%, and 26.74%, respectively. This trend is primarily attributed to the increasing size of the halogen atoms, which leads to better light absorption and charge transport properties, with iodine (I) yielding the highest theoretical conversion efficiency. These findings suggest that optimizing the halogen element in CsSnX3 can significantly enhance device performance, providing valuable theoretical guidance for the development of high-efficiency all-inorganic perovskite solar cells.
- Subjects
SOLAR cells; PEROVSKITE; PHOTOVOLTAIC power systems; HALOGENS; SIMULATION software; LIGHT absorption; IODINE
- Publication
Molecules, 2024, Vol 29, Issue 11, p2599
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules29112599