We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Formation of Aminocyclopentadienes from Silyldihydropyridines: Ring Contractions Driven by Anion Stabilization.
- Authors
Walker, Morgan M.; Chen, Shuming; Mercado, Brandon Q.; Houk, K. N.; Ellman, Jonathan A.
- Abstract
Abstract: Highly functionalized aminocyclopentadienes can be formed through the rearrangement of anions generated from readily prepared 6‐silyl‐1,2‐dihydropyridines by desilylation with fluoride. The scope and generality of the reaction was defined, and diverse transformations were performed on the highly functionalized products. A mechanism and driving force for the rearrangement were identified from experiments and DFT calculations.
- Subjects
CYCLOPENTADIENE; DIHYDROPYRIDINE; ANIONS; REARRANGEMENTS (Chemistry); DENSITY functional theory; SILYLATION
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 22, p6715
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201800596