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- Title
Spectral, Acid, and Coordination Properties of Dodecasubstituted Porphyrins.
- Authors
Pukhovskaya, S. G.; Ivanova, Yu. B.; Nam, Dao The; Semeikin, A. S.; Syrbu, S. A.; Mamardashvili, N. Zh.
- Abstract
The results of investigation of the interrelation between the geometric structure and coordination, acid, and spectral properties of a series of porphyrins with different systems of meso and β substituents are presented. The geometry of polysubstituted porphyrins was optimized at the DFT B3LYP/6-311G level of theory using Gaussian 09. It was shown that the dianionic forms of dodecasubstituted porphyrins hold promise for the development of highly efficient liquid sensors for metal cations.
- Subjects
ACIDS; PORPHYRINS; CHEMICAL detectors; METALLURGIC chemistry; CATIONS
- Publication
Russian Journal of General Chemistry, 2019, Vol 89, Issue 3, p586
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S107036321903040X