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- Title
Oxidation of β-dicarbonyl compounds with tert-butyl hydroperoxide in the presence of vanadyl acetylacetonate.
- Authors
Stepovik, L. P.; Gulenova, M. V.; Kalacheva, I. A.; Potkina, A. Yu.
- Abstract
Oxidation of β-dicarbonyl compounds with tert-butyl hydroperoxide in the presence of vanadyl acetylacetonate (benzene, 20°C) involves the activated methylene group with intermediate formation of trioxo derivatives and is accompanied by decomposition of carbon skeleton. The oxidation products are carbon dioxide, carboxylic acids, and tert-butyl and peroxy esters derived from the latter.
- Subjects
OXIDATION; CARBONYL compounds; PEROXIDES; ORGANIC acids; CARBENES; CARBON dioxide; CARBOXYLIC acids
- Publication
Russian Journal of General Chemistry, 2011, Vol 81, Issue 3, p550
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363211030182