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- Title
Change in the hybridization of the N→O group oxygen atom upon complex formation of pyridine and quinoline N-oxides with v-acceptors.
- Authors
Andreev, V. P.; Vapirov, V. V.; Nizhnik, Ya. P.; Aleshina, L. A.; Semenova, T. A.
- Abstract
It was shown on the basis of X-ray structural and NMR data that the ( sp 2→ sp 3) rehybridization of the oxygen atom of the N→O group can take place in reactions of heteroaromatic N-oxides with Lewis and Bronsted-Lowry acids. The hybridization type depends on the ligand and acceptor natures, composition of a complex, and spatial stresses arising during the complex formation.
- Subjects
MOLECULAR biology; CHALCOGENS; PYRIDINE; QUINOLINE; COMPLEX compounds
- Publication
Russian Journal of General Chemistry, 2008, Vol 78, Issue 5, p973
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363208050241