We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Synthesis and Structure of New [5]Ferrocenophane.
- Authors
Medved'ko, A. V.; Churakov, A. V.; Krut'ko, D. P.; Vatsadze, S. Z.
- Abstract
The first example of intramolecular diastereoselective domino reaction of ferrocene 1,1'-bis-enone to [5]ferrocenophane initiated with sodium ethoxide was found. The product is [5]ferrocenophane with two pyridyl and one ethoxy substituents arranged asymmetrically in a five-carbon bridge. Diffraction studies showed that ferrocene is in almost ideal eclipsed conformation. The fan conformation found in the crystal is also preserved in solution, which was determined by NMR spectroscopy.
- Subjects
FERROCENE; SODIUM
- Publication
Doklady Chemistry, 2023, Vol 513, Issue 2, p375
- ISSN
0012-5008
- Publication type
Article
- DOI
10.1134/S0012500823600840