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- Title
Kinetics study on cnt-supported RuKCo FTS catalyst in a fixed bed reactor.
- Authors
Trépanier, Mariane; Dion, Christopher A. Dorval; Dalai, Ajay K.; Abatzoglou, Nicolas
- Abstract
The rate of syngas (H2/CO) consumption over a RuKCo/CNT Fischer-Tropsch synthesis (FTS) catalyst was measured in a fixed bed microreactor at 210-225°C, 2-3.5 MPa, H2/CO feed molar ratios of 1-2.5, and gas hourly space velocity (GHSV) range of 2700-3600 h−1. The data have been used to model the kinetics of the FTS reactions within the range of the studied conditions. One empirical power law model and four semi-empirical kinetic models based on Langmuir-Hinshelwood-type equation have been evaluated. The best fitting was obtained with the equation:
- Subjects
SYNTHETIC gasoline; FISCHER-Tropsch process; CATALYSTS; MICROREACTORS; CHEMICAL kinetics; EQUATIONS
- Publication
Canadian Journal of Chemical Engineering, 2011, Vol 89, Issue 6, p1441
- ISSN
0008-4034
- Publication type
Article
- DOI
10.1002/cjce.20498