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- Title
Preparation and Electrochemical Properties of Sr-doped K<sub>2</sub>NiF<sub>4</sub>-type Cathode Material Pr<sub>1.7</sub>Sr<sub>0.3</sub>CuO<sub>4</sub> for IT-SOFCs.
- Authors
Ding, Z.; Guo, R.; Guo, W.; Liu, Z.; Cai, G.; Jiang, H.
- Abstract
A novel K2NiF4-type oxide Pr1.7Sr0.3CuO4 (PSCu) is studied to obtain its electrochemical properties as the cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs). The PSCu cathode powder and Ce0.8Sm0.2O1.9 (SDC) electrolyte powder were synthesized by sol-gel method and glycine-nitrate method, respectively. The crystal structure of PSCu powder and PSCu-SDC composite powder were identified with X-ray diffraction (XRD). It is shown that PSCu belongs to tetragonal K2NiF4-type and has good chemical compatibility with SDC. The thermal expansion coefficient (TEC) of PSCu is close to that of SDC. The conductivity of PSCu tested with four-probe method exhibits a semiconductor-pseudometal transformation at 400-450 °C, where the maximum conductivity of 103.6 S cm−1 is obtained. The polarization test indicates the area specific resistance (ASR) of PSCu decreases with increasing temperature, reaching 0.11 Ω cm2 at 800 °C. The activation energy of oxygen reduction reaction during 600-800 °C is 1.19 eV. The single fuel cell performance test reveals the open circuit voltage (OCV) and resistivity of PSCu reduce with increasing temperature, but the power density ascends with increasing temperature. The maximal power density is 243 mW cm−2 at 800 °C, and the corresponding current density and OCV are 633 mA cm−2 and 0.77 V, respectively.
- Subjects
ELECTROCHEMICAL research; CATHODES; SOLID oxide fuel cells; SOL-gel processes; X-ray diffraction
- Publication
Fuel Cells, 2016, Vol 16, Issue 2, p252
- ISSN
1615-6846
- Publication type
Article
- DOI
10.1002/fuce.201500140