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- Title
Novel Methylaluminoxane-Activated Neodymium Isopropoxide Catalysts for 1,3-Butadiene Polymerization and 1,3-Butadiene/Isoprene Copolymerization.
- Authors
Hu, Yanming; Dong, Weimin; Masuda, Toshio
- Abstract
The homo- and copolymerizations of 1,3-butadiene and isoprene are examined by using neodymium isopropoxide [Nd(O i-Pr)3] as a catalyst, in combination with a methylaluminoxane (MAO) cocatalyst. In the homopolymerization of 1,3-butadiene, the binary Nd(O i-Pr)3/MAO catalyst works quite effectively, to afford polymers with high molecular weight (
- Subjects
COPOLYMERS; POLYMERIZATION research; BUTADIENE; NEODYMIUM compounds; CATALYSTS
- Publication
Macromolecular Chemistry & Physics, 2013, Vol 214, Issue 19, p2172
- ISSN
1022-1352
- Publication type
Article
- DOI
10.1002/macp.201300383