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- Title
The redox behavior of 9-nickelafluorenyl sandwich complexes.
- Authors
Fulvio Rossi; Fabrizia de Biani; Piero Zanello; Piotr Buchalski
- Abstract
Abstract A collection of nickelocene and cobaltocene analogs with one or two nickelafluorenyl rings has been recently synthesized starting from 9-nickelafluorenyllithium complex. The redox ability of the whole series of derivates has been investigated by electrochemical techniques, and the nature of the frontier orbitals responsible for the electron transfer activity of this class of compounds has been supported by extended Hückel calculations.
- Subjects
ELECTROCHEMICAL analysis; OXIDATION-reduction reaction; COMPLEX compounds; ORGANONICKEL compounds; METALLOCENES; MOLECULAR orbitals; CHARGE exchange; CHEMISTRY mathematics
- Publication
Journal of Solid State Electrochemistry, 2009, Vol 13, Issue 10, p1505
- ISSN
1432-8488
- Publication type
Article
- DOI
10.1007/s10008-009-0833-2