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- Title
Crystal Structure, Thermal Expansivity and High-Temperature Vibrational Spectra on Natural Hydrous Rutile.
- Authors
Wang, Sha; Zhang, Jinhua; Smyth, Joseph R.; Zhang, Junfeng; Liu, Dan; Zhu, Xi; Wang, Xiang; Ye, Yu
- Abstract
A natural rutle sample was measured by in situ high-temperature X-ray diffraction (XRD) patterns, as well as Raman and Fourier transform infrared (FTIR). Crystal structure is refined on the sample with 1.4 mol.% Fe and 510±120 ppmw. H2O. The unit-cell and TiO6 octahedral volumes are expanded by 0.7%–0.8% for Fe3+ incorporation, as compared with the reported Ti-pure samples. The volumetric thermal expansion coefficient (α, K−1) could be approximated as a linear function of T (K): 4.95(3)×10−9×T+21.54(5)×10−6, with the averaged value α0=30.48(5)×10−6 K−1, in the temperature range of 300–1500 K. The internal Ti-O stretching (A1g and B2g) and O-Ti-O bending (Eg) modes show 'red shift', whereas the multi-phonon process exhibits 'blue shift' at elevated temperature. The rotational mode (B1g) for TiO6 octahedra is nearly insensitive to temperature variations. The OH-stretching bands at 3 279 and 3 297 cm−1 are measured by high-temperature spectroscopy experiments. Both the IR-active and Raman-active OH-stretching modes shift to lower frequencies at higher temperature, with the signal intensities decreasing. And after quenching, we expect about 43% dehydration around 873 K, and 85% dehydration at 1 273 K for this hydrous sample.
- Subjects
VIBRATIONAL spectra; CRYSTAL structure; HYDROUS; RUTILE; EXPANSION of solids; THERMAL expansion
- Publication
Journal of Earth Science, 2020, Vol 31, Issue 6, p1190
- ISSN
1674-487X
- Publication type
Article
- DOI
10.1007/s12583-020-1351-5