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- Title
Effects of Cycloaminomethyl Derivatives of Sterically Hindered Dihydroxybenzenes on Radiation-Induced Reactions Involving Peroxyl and Alkyl Radicals.
- Authors
Ksendzova, G. A.; Ostrovskaya, N. I.; Sorokin, V. L.; Shadyro, O. I.
- Abstract
The influence of cycloaminomethyl derivatives of 4-tert-butyl-1,2-dihydroxybenzene, 3,5-di-tert-butyl-1,2-dihydroxybenzene, and 4,6-di-tert-butyl-1,3-dihydroxybenzene with different substituent ring sizes on the formation of n-hexane radiolysis products in the presence and absence of oxygen was studied. It was shown that the activity of sterically hindered diphenol derivatives toward alkyl radicals increased with the ring size in the side substituent, while the activity toward peroxyl radicals remained at the same level.
- Subjects
ALKYL radicals; RADIOLYSIS; MANNICH bases
- Publication
High Energy Chemistry, 2022, Vol 56, Issue 5, p344
- ISSN
0018-1439
- Publication type
Article
- DOI
10.1134/S0018143922050083